Here, I’ve got some common beginner mistakes (that I experienced while learning psql).
Note that there are many mistakes you can make not listed here! Good luck!

Databases

create database dbName - create a database with name dbName
\c dbName - connect to database with name dbName
\list - lists the databases (and various properties)

Running SQL

\i sqlFile - runs (or interprets) the SQL file on the database

Tables (Relations)

\dt - gives you a list of tables (describe tables)

Display Options

\pset specialValue toDisplay - sets options for displaying special values e.g. \pset null ‘UH OH NULLY WULLY’ will display all null values as ‘UH OH NULLY WULLY’